Set up an electric circuit with an LED and a break in the wire, put both ends of wire into a solution/molten substance. If the LED lights up then there is a current flowing, this will only be able to happen if the solution is conducting: so it must be an electrolyte. Conversely if the LED does not light up then there is no current flowing, and so the solution has not conducted electricity meaning it must be a nonelectrolyte.
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